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Critical point

Understand critical temperature and critical pressure, what changes near the critical region, and how to interpret Tc/Pc in practice.

The critical point is where the distinction between liquid and vapor disappears. Above the critical temperature and pressure, the fluid becomes supercritical and there is no classic boiling/condensing phase change.

Two key numbers: Tc and Pc

  • Critical temperature (Tc): above Tc, you cannot liquefy the fluid by increasing pressure alone.
  • Critical pressure (Pc): the pressure at the critical point. Near Pc and Tc, properties can change rapidly with small shifts in temperature or pressure.

Why the critical region matters

  • Charts and property tables can show strong gradients near the critical point; numerical results may become more sensitive to inputs.
  • For certain systems (e.g., transcritical CO2), the operating line crosses the critical region and "condensation" is replaced by gas cooling.
  • For blends, the "critical point" can be less sharp in practice (often a critical curve/region), so published Tc/Pc should be treated as a helpful reference, not a universal boundary for all behaviors.

Explore it in FluidTool

Use the calculator to sweep temperature and pressure near Tc/Pc, compare the resulting density/enthalpy gradients, and cross-check the critical numbers listed on the fluid data page (e.g., R134a data sheet). Property Lookup also helps you see how Psat/Tsat behavior starts to flatten as you approach the critical region.

Related

  • Back to Wiki
  • Example: CO2 data sheet
  • Open the Props tool

Transcritical CO2 (R744) cycle

Learn what transcritical CO2 (R744) means, why PT charts stop working above the critical point, and how to interpret gas cooler vs condenser behavior without using "target pressures".

Gauge vs absolute pressure (psig vs psia)

Understand gauge vs absolute pressure (psig vs psia), why thermodynamic properties use absolute pressure, and how to convert safely (Patm varies with altitude and weather).

Table of Contents

Two key numbers: Tc and Pc
Why the critical region matters
Explore it in FluidTool
Related